Product ID:A/W 46 DOVER, 33-478
MSDS Date:10/07/1997
FSC:9150
NIIN:00N089160
Status Code:A
MSDS Number: CHSVC

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 918-495-4700;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

REFINED PETROLEUM OIL(S) CONTAINING INGS 2-8

RTECS: 9999999ZZ

Fraction By Weight: 98-100%

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-88-4

RTECS: PY8040501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM IDSTILLATES, SOLVENT-REFINED

CAS: 64741-89-5

RTECS: PY8041501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT DEWAXED HEAVY

CAS: 64742-65-0

RTECS: PY8038501

OSHA PEL N/K

ACGIH TLV: N/K

HYDROTREATMENT

RTECS: 9999999ZZ

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)

CAS: 64742-55-8

RTECS: PY8036501

OSHA PEL N/K

ACGIH TLV: N/K

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE)

CAS: 64742-54-7

RTECS: PY8035501

OSHA PEL N/K

ACGIH TLV: N/K

HIGHLY REFINED BASE OIL

CAS: 72623-87-1

OSHA PEL N/K

ACGIH TLV: N/K

ONLY UPON ADVICE OF PHYS. SEEK MED ATTN IMMED.

RTECS: 9999999ZZ

STREAM IS MED EMER. SEEK MED ATTN IMMED. NOTES TO

RTECS: 9999999ZZ

MSDS IS BETWEEN 200-399 SUS @ 100F. UPON INGEST,

RTECS: 9999999ZZ

OF LG QTYS, CAREFUL GASTRIC LAVAGE/EMESIS MAY BE

RTECS: 9999999ZZ

INTRAMUSCULAR INJECTION REQUIRES PROMPT SURGICAL

RTECS: 9999999ZZ

DISP. (SEE WASTE DISP SECTION). LG SPILLS

RTECS: 9999999ZZ

EXPOS POTNTL. POTNTL EXPOS MAY REQ USE OF NIOSH

RTECS: 9999999ZZ

TEMPORARY DIKES TO AVOID PROD MIGRATION & TO ASSIST

RTECS: 9999999ZZ

SEWERS, GROUND WATER, DRAINAGE DITCHES/SURF WATER.

RTECS: 9999999ZZ

APPROPRIATE FEDERAL, STATE & LOCAL AUTHORITIES.

RTECS: 9999999ZZ

REGIONAL EPA OFFICE FOR GUIDANCE

RTECS: 9999999ZZ

PROT MEASURES DURING REPAIR & MAINTENANCE OF

RTECS: 9999999ZZ

EQUIP, AS NEC, TO REMOVE MATL RESIDUES. USE GLOVES

RTECS: 9999999ZZ

NITRILE RUBB & PROT WORK CLTHG IF DIRECT CONT IS

RTECS: 9999999ZZ

TO BE INJECTED INTO SKIN FROM HIGH PRESS LEAKS IN

RTECS: 9999999ZZ

REMOVE CONTAMD CLTHG. LAUNDER BEFORE REUSE. FOR

RTECS: 9999999ZZ

BELOW APPLICABLE WORKPLACE EXPOSURE LEVELS AS

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: IN ENCLOSED SPACES/WHEN
HOT, VAPS MAY REACH CONCS SUFFICIENT TO CAUSE DROW, DIZZ, HEADACHE,
NAUS, OR LUNG IRRIT. ELEVATED MIST CONCS WELL ABOVE APPLIC
WORKPLACE EXPOS LEVELS MAY CAUSE SE V LUNG DMG. DERMAL: MAY CAUSE
MILD TRANSIENT IRRIT. EYE: MAY CAUSE MILD TRANSIENT IRRIT. INGEST:
IF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SWALLOWED, MATL MAY ENTER LUNGS BY
ASPIR & CAUSE SEV DMG. UPON INGEST, GI DISCOMFORT, DIARR, & HDCH
MAY OCCUR. INJECTION: INJECTION UNDER SKIN, IN MUSCLE/INTO BLOOD
STREAM MAY CAUSE IRRIT, I NFLAMM, SWELL/SEV, PERM TISS DMG. MOST
DMG OCCURS DURING FIRST FEW HRS. TOXICITY: GENERALLY OF LOW ORDER
OF (SUPDAT)
Medical Cond Aggravated by Exposure:NONE.

First Aid:INHAL: MOVE TO FRESH AIR. IF VICTIM IS NOT BRTHG, IMMED BEGIN
CARDIOPULM RESUSCITATION (CPR). IF BRTHG IS DFCLT; 100 PERCENT
HUMIDIFIED OXYG SHOULD BE GIVEN BY QUALIFIED INDIVIDUAL. SEEK MED
ATTN IMME D. SKIN: WASH EXPOSED SKIN W/SOAP & WATER. REMOVE CONTAMD
CLTHG. LAUNDER BEFORE REUSE. SEEK MED ATTN IF TISS APPEARS DMGD/IF
IRRIT PERSISTS. EYES: FLUSH W/LG VOL OF WATER FOR AT LST 15 MINS.
(SUPDAT)

Flash Point Method:OC
Flash Point:>365F,>185C
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:NONE. USE NIOSH APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING. MATERIAL MAY BE
IGNITED BY SPARKS OR FLAMES.

Spill Release Procedures:REMOVE ALL IGNIT SOURCES. ISOLATE AREA OF
SPILL & RESTRICT ACCESS TO PERSONS WARING PROT CLTHG. VENTILATE
AREA OF RELEASE, AS NEC, TO DISPERSE VAPS & MISTS. SM SPILLS:
ABSORB RELEASED MATL W/NON-COMBU ST ABSORB. PLACE INTO CNTNRS FOR
LATER (ING 14)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL DRY WELL VENTILATED
AREA. DO NOT APPLY HEAT/FLAME TO CNTNR. KEEP SEPARATE FROM STRONG
OXIDIZING AGENTS.
Other Precautions:EMPTY CNTNRS MAY CNTN COMBUST PROD RESIDUES WHICH
COULD IGNITE W/EXPLO FORCE. CONSULT APPROP FED, STATE & LOC AUTH
BEFORE REUSING, RECONDITIONING, RECLAIMING, RECYCLING/DISPOSING OF
EMPTY CNTNRS AND/O R WASTE RESIDUES OF THIS PROD. (ING 20)

Respiratory Protection:AT ELEVATED TEMPERATURES/IN ENCLOSED AREAS,
VAPOR/MIST CONCS MAY EXCEED APPLIC WORKPLACE EXPOSURE LEVELS. USE
NIOSH APPRVD ORGANIC VAPOR/MIST CHEMICAL CARTRIDGE RESPIRATOR WHEN
ELEVATED AIRBORNE CONCS ARE ANTICIPATED.
Ventilation:USE IN WELL VENTILATED AREA. IN CONFINED SPACE, MECH VENT
MAY BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS (ING 25)
Protective Gloves:IMPERVIOUS; SUCH AS HEAVY NITRILE RUBB.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
BODY-COVERING CLOTHES TO AVOID PRLNGD/RPTD EXPOSURE.
Work Hygienic Practices:LAUNDER CONTAMINATED WORK CLOTHES BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV: 0.86-0.89 (H*2O =1). VP: 1 X 10-5 TO 2X 10-4 @ 25C. HAZ
DECOMP PROD: PHOSPHOROUS, SULFUR & ZINC. EFTS OF OVEREXP: TOX.
CHRONIC: PRLNGD AND/OR FREQUENT CONT MAY CAUSE DRYING, CRACKING
(DERM) OR FOLLICULITIS. FIRST AID PROC: SEEK MED ATTN IF PAIN,
EXCESS TEARING/IRRIT PERSISTS. INGEST: INDUCE VOMIT (ING 9)

Boiling Pt:B.P. Text:>560F,>293C
Vapor Pres:SUPDAT
Vapor Density:>1
Spec Gravity:SUPDAT
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER LIQUID, MILD PETROLEUM ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
THIS PRODUCT MAY REACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:(THERMAL, UNLESS OTHERWISE SPECIFIED):
CO*2, CO WITH INCOMPLETE COMBUSTION, AND POTENTIAL TRACE OXIDES OF
(SUPDAT)

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . IT IS
RESPONSIBILITY OF USER TO DETERM IF MATL IS HAZ WASTE @ TIME OF
DISP. DETERM COMPLIANCE STATUS W/ALL APPLIC REQUIREMENTS PRIOR TO
DISP. CONT RCRA /SUPERFUND HOTLINE AT (800)424-9346/YOUR (ING 19)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.